And on his 141st appearance for Arsenal, Ozil, who is well-known for his creative abilities, subsequently became the fastest player in Premier League history to reach 50 assists.
And the victory was sealed for Arsenal in the 77th minute, when Henrikh Mkhitaryan fired in a third from the edge of the box for his first Premier League goal for the Gunners.
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Arsenal, which had lost eight of its previous 14 matches in all competitions, remains in sixth place and trails fourth-placed Tottenham Hotspur by 10 points ahead of its rival's trip to Bournemouth later yesterday.
Arsenal striker Pierre-Emerick Aubameyang has given manager Arsene Wenger his backing and cited the Frenchman as being key to his move to the club in January. They hold a 2-0 lead against Milan and will host the Serie A giants in the second leg on Thursday.
The 3-0 win also means Cech has registered his 200th clean sheet in the top-flight, across spells with both Chelsea and Arsenal.
"I think my timing was quite good to put him off, but sometimes you do the right thing and you are short or you go the wrong way, but this time it all clicked".
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Indeed, Deeney's penalty miss drew the biggest cheer of the day from the home support and it could be argued the boos which preceded his spot kick got the Deeney.
That's mainly because the duo played together at Borussia Dortmund before Mkhitaryan was sold to Manchester United.
"I'm feeling really better; in January I didn't play a lot so it was hard when I came here, but I'm feeling better and I try to do my best of course for the team and for the club", Aubameyang told BBC Africa Sport.
"The spirit kept us out of trouble".
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The Gunners started the match with their usual 4-2-3-1 with Mohamed Elneny playing as part of a two-man pivot in midfield alongside Granit Xhaka. They'll next play against Ramadan Sobhi's Stoke City in the league on April 1.